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ASTM D6144-12
Standard Test Method for Analysis of AMS (α-Methylstyrene) by Capillary Gas Chromatography
Automaticky preložený názov:
Štandardná skúšobná metóda pre analýzu AMS ( a - metylstyrén ) pomocou kapilárnej plynovej chromatografie
NORMA vydaná dňa 1.12.2012
Informácie o norme:
Označenie normy: ASTM D6144-12
Poznámka: NEPLATNÁ
Dátum vydania normy: 1.12.2012
Kód tovaru: NS-33990
Počet strán: 5
Približná hmotnosť: 15 g (0.03 libier)
Krajina: Americká technická norma
Kategória: Technické normy ASTM
Anotácia textu normy ASTM D6144-12 :
Keywords:
acetophenone, alpha methylstyrene, AMS, analysis by gas chromatography, benzene, butenylbenzene, butylbenzene, catechol, cumene, cymene, phenol, propylbenzene, toluene, ICS Number Code 71.040.50 (Physicochemical methods of analysis)
Doplňujúce informácie
| Significance and Use | |||
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5.1 This test method is suitable for setting specifications on the materials referenced in 1.2 and for use as an internal quality control tool where AMS is produced or is used in a manufacturing process. It may also be used in development or research work involving AMS. 5.2 This test method is useful in determining the purity of AMS with normal impurities present. If extremely high boiling or unusual impurities are present in the AMS, this test method would not necessarily detect them and the purity calculation would be erroneous. |
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| 1. Scope | |||
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1.1 This test method covers the determination of the purity of AMS (α-methylstyrene) by gas chromatography. Calibration of the gas chromatography system is done by the external standard calibration technique. 1.2 This test method has been found applicable to the measurement of impurities such as cumene, 3-methyl-2-cyclopentene-1-one, n-propylbenzene, tert-butylbenzene, sec-butylbenzene, cis-2-phenyl-2-butene, acetophenone, 1-phenyl-1-butene, 2-phenyl-2-propanol, trans-2-phenyl-2-butene, m-cymene, p-cymene, and phenol, which are common to the manufacturing process of AMS. The method has also been found applicable for the determination of para-tertiary-butylcatechol typically added as a stabilizer to AMS. The impurities in AMS can be analyzed over a range of 5 to 800 mg/kg by this method. (See Compound |
Repeatability (r) |
Reproducibility (R) |
Range Studied |
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Acetone |
1.61 + 0.035*Acetone |
0.47 + 1.10*Acetone |
0.5 – 26 |
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Cumene |
−0.46 + 0.031*Cumene |
7.88 + 0.19*Cumene |
45 – 290 |
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nPropylbenzene (NPB) |
2.11 + 0.03*NPB |
−7.81 + 0.37*NPB |
55 – 195 |
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Phenol |
1.84 |
3.65 + 0.58*Phenol |
1 – 40 |
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tertButylbenzene (TBB) |
−1.22 + 0.035*TBB |
3.63 + 0.087*TBB |
150 – 650 |
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secButylbenzene (SBB) |
4.23 + 0.019*SBB |
21.60 + 0.25*SBB |
200 – 765 |
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mCymene |
0.31 + 0.035*mCymene |
2.34 + 0.35*mCymene |
2 – 50 |
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oCymene |
1.63 |
8.00 |
29 – 31 |
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pCymene |
5.12 |
15.79 |
10 – 18 |
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cis-2-Phenyl-2-Butene (CPB) |
0.17 + 0.030*CPB |
5.39 + 0.11*CPB |
50 – 225 |
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trans-2-Phenyl-2-Butene (TPB) |
1.57 |
0.54 + 0.20*TPB |
19 – 70 |
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1-Phenyl-1-Butene (PB) |
4.00 + 0.018*PB |
0.17 + 0.19*PB |
0.2 – 735 |
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Acetophenone (AP) |
–1.09 + 0.15*AP |
1.17 + 0.63*AP |
15 – 115 |
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para-tert-Butylcatechol (PTBC) |
2.21 |
17.82 |
10 – 19 |
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2-Methylbenzofuran (MBF) |
0.33 + 0.76*MBF |
0.75 + 0.60*MBF |
1 – 2 |
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2-Phenylpropion aldehyde (PPA) |
0.59 + 0.11*PPA |
0.29 + 0.23*PPA |
1.5 – 15 |
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α-Methylstyrene Oxide (AMSO) |
4.61 |
6.51 + 0.23*AMSO |
13 – 32 |
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DimethylBenzyl Alcohol (DMBA) |
0.38 |
0.55 + 2.03*DMBA |
0.1 – 1 |
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1.3 In determining the conformance of the test results using this method to applicable specifications, results shall be rounded off in accordance with the rounding-off method of Practice E29.
1.4 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.
1.5 This standard does not purport to address all the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. For specific hazard statements, see Section 8.
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Standard Practice for Preparation of Liquid Blends for Use as Analytical Standards |
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Standard Practice for Conducting an Interlaboratory Study to Determine the Precision of a Test Method |
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Standard Practice for Gas Chromatography Terms and Relationships (Includes all amendments and changes 4/28/2021). |
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Standard Practice for Using Significant Digits in Test Data to Determine Conformance with Specifications |
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Standard Guide for Quality Control and Quality Assurance Procedures for Aromatic Hydrocarbons and Related Materials |
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Standard Practice for Sampling and Handling Liquid Cyclic Products |
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Standard Practice for Installing Fused Silica Open Tubular Capillary Columns in Gas Chromatographs |
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Standard Terminology of Aromatic Hydrocarbons and Related Chemicals |
