ASTM D7414-18

5.1 A large number of compounds, such as aldehydes, ketones, esters, and carboxylic acids, are produced when oils react with atmospheric oxygen. Oxidation is measured using a common FT-IR spectral feature between 1800 and 1670 cm^–1 caused by the absorption of the carbonyl group present in most oxidation compounds. These oxidation products may lead to increased viscosity (causing oil thickening problems), acidity (causing acidic corrosion), and formation of sludge and varnish (leading to filter plugging, fouling of critical oil clearances and valve friction). Monitoring of oxidation products is therefore an important parameter in determining overall machinery health and should be considered in conjunction with data from other tests such as atomic emission (AE) and atomic absorption (AA) spectroscopy for wear metal analysis (Test Method D5185), physical property tests (Test Methods D445 and D6304), base reserve (Test Method D2896 and D4739), acid number tests (Test Methods D664 and D974) and other FT-IR oil analysis methods for nitration (Practice E2412), sulfate by-products (Test Method D7415), additive depletion (Test Method D7412), breakdown products and external contaminants (Practice E2412), which also assess elements of the oil’s condition, see Refs (1-6).

1.1 This test method covers monitoring oxidation in in-service petroleum and hydrocarbon based lubricants such as in diesel crankcase, motor, hydraulic, gear and compressor oils, as well as other types of lubricants that are prone to oxidation.

1.2 This test method uses Fourier Transform Infrared (FT-IR) spectrometry for monitoring build-up of oxidation products in in-service petroleum and hydrocarbon based lubricants as a result of normal machinery operation. Petroleum and hydrocarbon based lubricants react with oxygen in the air to form a number of different chemical species, including aldehydes, ketones, esters, and carboxylic acids. This test method is designed as a fast, simple spectroscopic check for monitoring of oxidation in in-service petroleum and hydrocarbon based lubricants with the objective of helping diagnose the operational condition of the machine based on measuring the level of oxidation in the oil.

1.3 Acquisition of FT-IR spectral data for measuring oxidation in in-service oil and lubricant samples is described in Practice D7418. In this test method, measurement and data interpretation parameters for oxidation using both direct trend analysis and differential (spectral subtraction) trend analysis are presented.

1.4 This test method is based on trending of spectral changes associated with oxidation of in-service petroleum and hydrocarbon based lubricants. Warnings or alarm limits can be set on the basis of a fixed minimum value for a single measurement or, alternatively, can be based on a rate of change of the response measured, see Ref (1).2

1.5 This test method is for petroleum and hydrocarbon based lubricants and is not applicable for ester based oils, including polyol esters or phosphate esters.

1.6 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.

1.7 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.

1.8 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.